Fluorocarbons

Fluorocarbons, sometimes referred to as perfluorocarbons or PFCs, are, strictly speaking, organofluorine compounds with the formula CxFy, i.e. they contain only carbon and fluorine. Compounds with the prefix perfluoro- are hydrocarbons, including those with heteroatoms, wherein all C-H bonds have been replaced by C-F bonds. Fluorocarbons and their derivatives are useful fluoropolymers, refrigerants, solvents, and anesthetics.

  • Puzzle About Passivation of Low-Friction, Hard Carbon Coatings Solved

    Electron density of two hydrogen-terminated (left) and fluorine-terminated (right) diamond surfaces: large fluorine atoms prevent the surfaces from interlocking and thus reduce friction. Fraunhofer Institute for Mechanics of Materials IWM

    Diamond and diamond-like carbon (DLC) are used as extremely durable surface coatings in frictional contacts: from aerospace components to razors. They reduce friction and wear in bearings and valves by means of so-called passivation layers, which prevent other materials from bonding to the coating. Until now, it was unclear how these passivation layers should be designed to achieve minimal friction. Researchers at the Fraunhofer Institute for Mechanics of Materials IWM, MicroTribology Centrum µTC, have now achieved a breakthrough in understanding the relationship between passivation and friction. The unexpected results have been published in the journal "ACS Applied Materials & Interfaces".